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鍙戝竷鏃堕棿锛?020-03-27

鏈綉璁?/span>锛堝寲瀛﹀寲宸ュ闄級2H-姘潅鐜笝鐑槸鏈€灏忕殑涓€绫讳笉楗卞拰涓夊厓鍚爱鐜潅鐜寲鍚堢墿銆傚洜鍏跺叿鏈夎緝澶х殑鐜紶鍔涜€屾槗浜庡彂鐢熷紑鐜弽搴旓紝鍦ㄥ悎鎴愭湁鏈哄寲瀛﹂鍩熷叿鏈夐潪甯稿箍闃旂殑搴旂敤鍓嶆櫙銆傜劧鑰岋紝浼犵粺鐨?/span>2H-姘潅鐜笝鐑紑鐜繃绋嬪ぇ澶氬眬闄愪簬浣跨敤鏄傝吹鐨勮繃娓¢噾灞炲偓鍖栧墏鎴栧湪楂樻俯涓嬫墠鑳借繘琛屻€?/span>

杩戞棩锛屾垜鏍″寲瀛﹀寲宸ュ闄㈠淇婃暀鎺堝洟闃熷拰鍗庝腑甯堣寖澶у鑲栨枃绮炬暀鎺堝洟闃熷悎浣滐紝鍦ㄥ彲瑙佸厜淇冭繘鐨?/span>2H-姘潅鐜笝鐑紑鐜畼鑳藉寲鍙嶅簲鏂归潰鍙栧緱浜嗘渶鏂扮爺绌惰繘灞曘€傜爺绌跺彂鐜帮紝浣跨敤浜氱鍩鸿姵鍩哄寲鍚堢墿浣滀负鑷敱鍩哄彈浣擄紝鍙湁鏁堟崟鎹夊厜璇卞2H-姘潅鐜笝鐑紑鐜墍浜х敓鐨勮嚜鐢卞熀闃崇瀛愪腑闂翠綋銆傝鍙嶅簲涓?/span>1,2,4-鍣佷簩鍞戝寲鍚堢墿鐨勫厜鍖栧鍚堟垚鎻愪緵浜嗕竴鏉$豢鑹查珮鏁堢殑閫斿緞锛堝浘1锛夈€傝椤圭爺绌舵垚鏋滀互銆?/span>[3+2]-Cycloaddition of 2H鈥慉zirines with Nitrosoarenes: Visible-Light-Promoted Synthesis of 2,5-Dihydro-1,2,4-oxadiazoles銆嬩负棰樺彂琛ㄤ簬缇庡浗鍖栧浼氱殑銆婃湁鏈哄揩鎶ャ€嬩笂锛?/span>Org. Lett. 2019, 21, 4234-4238锛岃嚜鐒舵寚鏁版湡鍒婏紝IF = 6.555锛夈€傛垜鏍″寲瀛﹀寲宸ュ闄㈢澹爺绌剁敓钄″疂璐典负璇ヨ鏂囩殑绗竴浣滆€咃紝瀹夊窘澶у涓鸿鏂囩殑绗竴閫氳鍗曚綅銆傚悓鏃讹紝璇ヨ棰樼粍杩樺埄鐢ㄥ彲瑙佸厜浣滀负缁胯壊鑳芥簮锛屽疄鐜颁簡3-閰板熀鍠瑰枖鍟夐叜锛?/span>Adv. Synth. Catal. 2020, DOI:10.1002/adsc.202000116锛夈€佽壊铻ㄩ叜锛?/span>Sci. Bull. 2019, 64, 337; Chem. Asian J. 2019, 14, 3269;锛夌瓑澶氱閲嶈鍚爱鏉傜幆鍖栧悎鐗╃殑鍏夊寲瀛﹀悎鎴愩€?/span>

鍥?span lang="EN-US">1. 1,2,4-鍣佷簩鍞戠殑鍏夊寲瀛﹀悎鎴愬弽搴?/span>

鍦ㄤ笂杩扮爺绌跺熀纭€涓婏紝璇ュ洟闃熻繎鏈熷湪鑻卞浗鐨囧鍖栧瀛︿細鐨勬棗鑸版湡鍒娿€婂寲瀛︾ぞ浼氳瘎璁恒€嬩笂鍦ㄧ嚎鍙戣〃棰樹负Visible Light-Promoted Ring-Opening Functionalization of Three-Membered Carbo- and Heterocycles鐨勭患杩版枃绔狅紝瀵瑰寘鎷?/span>2H-姘潅鐜笝鐑€佺幆涓欑兎銆佺幆涓欑儻銆佺幆姘т箼鐑枫€佹爱鏉傜幆涓欑兎鍜屽搼鍡瓑鍏ぇ绫讳笁鍏冪幆鐘跺寲鍚堢墿鐨勫厜璇卞寮€鐜畼鑳藉寲鍙嶅簲鍋氫簡鍏ㄩ潰鍒嗘瀽鎬荤粨銆傛枃绔犱粠鍚堟垚鍏夊寲瀛︾殑鑳屾櫙鍒囧叆锛屽垎绫讳粙缁嶄簡涓婅堪鍏涓夊厓鏉傜幆鍖栧悎鐗╁湪鍏変績寮€鐜畼鑳藉寲鍙嶅簲鏂归潰涓嶅悓鐨勫弽搴旂被鍨嬨€佸弽搴斿師鐞嗗拰灞€闄愭€э紝骞跺睍鏈涗簡杩欑被鍖栧悎鐗╁湪鍚堟垚鍏夊寲瀛﹂鍩熸湭鏉ョ殑鍙戝睍鏂瑰悜锛堝浘2锛夛紙 Chem. Soc. Rev. 2020, DOI:10.1039/C9CS00523D, IF = 40.443锛夈€傝璁烘枃鐨勭涓€浣滆€呮槸鎴戞牎纭曞+鐮旂┒鐢熶綍鍚戝锛屽畨寰藉ぇ瀛︿负绗竴閫氳鍗曚綅銆?/span>

鍥?span lang="EN-US">2. 鍙鍏夎瀵间笁鍏冪幆鐨勫紑鐜畼鑳藉寲鍙嶅簲

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